Sequential enolboration/hydroformylation/aldol addition: a new one-pot cascade reaction for the regio- and diastereoselective formation of carbocyclic quaternary centres from acyclic olefins.
نویسندگان
چکیده
Starting from unsaturated carbonyl compounds a mild new cascade reaction involving enolboration, rhodium-catalysed hydroformylation and intramolecular aldol addition in a regio- and diastereoselective fashion leads to cyclic compounds containing highly-functionalised quaternary carbon centres.
منابع مشابه
Organocatalytic asymmetric strategies to carbocyclic structures by γ-alkylation-annulation sequences.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 2 12 شماره
صفحات -
تاریخ انتشار 2004